New models of monooxygenase on the basis of Sn(II) compounds |
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| Authors: | N Z Muradov A E Shilov and A A Shteinman |
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| Institution: | (1) Institute of Chemical Physics, Moscow, USSR |
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| Abstract: | The data on the selectivity of various C–H bonds and the stereochemical course of the reaction in the known chemical systems simulating monooxygenase, do not agree with the oxenoid mechanism postulated for these reactions, but correspond to the interaction of saturated hydrocarbons with the OH radical intermediate. On the basis of organic compounds of Sn(II) in aprotic media, new systems have been developed which selectively oxidize alkanes to alcohols in the presence of O2 in the coupled process and display many characteristics of the oxenoid reactions.
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