Stibinidenkomplexe: Verbindungen mit trigonal planar koordiniertem antimon |
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| Authors: | Ute Weber Laszlo Zsolnai Gottfried Huttner |
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| Institution: | Lehrstuhl für Synthetische Anorganische Chemie, Fakultät für Chemie, Universität Konstanz, Postfach 5560, D - 7750 Konstanz B.R.D. |
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| Abstract: | Intensively coloured stibinidene complexes (LnM)2SbR (LnM = (CO)5Cr; R = tBu, Cl, I, EtS. LnM = C5H5(CO)2Mn; R = Cl. LnM = CH3C5H4(CO)2Mn; R = Br) which contain trigonally planar coordinated Sb(+1) with the stibanediyl ligand stabilized by M Sb(R) M-π-bonding have been obtained. Their synthesis and properties as well as an X-ray structure determination of CH3C5H4(CO)2Mn]2SbBr are described. |
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