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Titanocene(II)-promoted carbonyl allenation utilizing 1,1-dichloroalk-1-enes |
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| Authors: | Shono Tomohiro Ito Kenji Tsubouchi Akira Takeda Takeshi |
| Institution: | Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo, 184-8588, Japan. |
| Abstract: | Treatment of 1,1-dichloroalk-1-enes with Cp2TiP(OEt)3]2 produced organotitanium species, which afford allenes on treatment with aldehydes and ketones. |
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