A capping methodology for the synthesis of lower mu-oxo-phthalocyaninato silicon oligomers |
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| Authors: | Cammidge Andrew N Nekelson Fabien Helliwell Madeleine Heeney Martin J Cook Michael J |
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| Institution: | Wolfson Materials and Catalysis Centre, School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich, UK NR4 7TJ. a.cammidge@uea.ac.uk |
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| Abstract: | A mixed condensation of a substituted and unsubstituted silicon phthalocyanine monomer, in which the former serves as a "cap" to a growing oligomeric chain, provides unprecedented access to a mixed dimer, trimers, and a tetramer. An important element of product control can be achieved by changing the ratio of the precursor monomers. |
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