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钼网衬底上大面积硅纳米线的制备及其光催化性能研究
引用本文:黄奔,李玄泽,王磊,夏静,朱丹丹,孟祥敏.钼网衬底上大面积硅纳米线的制备及其光催化性能研究[J].影像科学与光化学,2016,34(3):257-264.
作者姓名:黄奔  李玄泽  王磊  夏静  朱丹丹  孟祥敏
作者单位:中国科学院 理化技术研究所 光化学与光功能材料重点实验室, 北京 100190
基金项目:国家重点基础研究发展规划项目(973项目;2012CB932401),中国科学院战略性先导科技专项(XDA09040203)
摘    要:硅纳米材料广泛应用于光功能导向的各个领域,发展针对光功能应用及一维硅纳米结构的规模化可控制备方法,实现硅纳米结构的宏量制备,将为硅纳米结构的应用提供材料保障。本文采用简单的化学气相沉积法成功地在Mo网衬底上制备了大面积的硅纳米线(SiNWs),并通过扫描电子显微镜、透射电子显微镜、X射线粉末衍射仪、拉曼光谱仪,对制备的SiNWs进行了详细的研究。通过在低功率紫外光照射下SiNWs对罗丹明B和甲基蓝的光降解能力的研究,发现在Mo网衬底上生长的SiNWs对于有机染料具有很好的降解能力。

关 键 词:硅纳米线  化学气相沉积法  Mo网衬底  光催化  
收稿时间:2016-04-01

Large-scale Synthesis of Silicon Nanowires on Molybdenum Nets for High-efficiency Photodegradation
HUANG Ben,LI Xuanze,WANG Lei,XIA Jing,ZHU Dandan,MENG Xiangmin.Large-scale Synthesis of Silicon Nanowires on Molybdenum Nets for High-efficiency Photodegradation[J].Imaging Science and Photochemistry,2016,34(3):257-264.
Authors:HUANG Ben  LI Xuanze  WANG Lei  XIA Jing  ZHU Dandan  MENG Xiangmin
Institution:Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
Abstract:Si nano-materials are wildly used in the field of photocatalyst, solar cell, photodetector due to their excellent photo-absorption ability. So the controlled and large-scale synthesis of one dimensional Si nano-materials becomes the key which affects their applications. In this report, we used a simple chemical vapor deposition (CVD) method to grow large-scale Si nanowires (SiNWs) on molybdenum (Mo) nets substrate. And the characteristics of SiNWs were detailedly analyzed by scanning electron microscope, transmission electron microscope, X-ray diffraction and Raman spectrum. Moreover, the photocatalytic properties of as-grown SiNWs were examined by the photodegradation of Rhodamine B and Methylene Blue under low power ultraviolet (UV) light. In addition, the results show that SiNWs growing on Mo nets substrate have a high photodegration efficient for organic dyes.
Keywords:Si nanowires  CVD  Mo nets substrate  photocatalyst
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