Self-organization of porphyrin units induced by magnetic field during sol-gel polymerization |
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Authors: | Lerouge Frédéric Cerveau Geneviève Corriu Robert J P Stern Christine Guilard Roger |
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Affiliation: | Laboratoire de Chimie Moléculaire et Organisation du Solide, UMR 5637, Université Montpellier II, cc 007, Place E. Bataillon, F-34095, Montpellier Cedex 5, France. |
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Abstract: | The use of a magnetic field as a controlling factor during the hydrolysis-polycondensation of porphyrin precursors substituted by Si(OR)(3) groups, induces a self-organization of porphyrin moieties due to the stacking of these units in the hybrid material and this study also confirms the effect of the magnetic field in the nano- and micrometric organization during the kinetically controlled polycondensation process. |
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