Novel triptycene-based cylindrical macrotricyclic host: synthesis and complexation with paraquat derivatives |
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| Authors: | Zong Qian-Shou Chen Chuan-Feng |
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| Affiliation: | Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China. |
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| Abstract: | [reaction: see text] A novel triptycene-based cylindrical macrotricyclic polyether containing two dibenzo[24]crown-8 cavities has been synthesized and proved to be a highly efficient host for the complexation with paraquat derivatives. Consequently, a new kind of very stable pseudorotaxane-type complex was formed in solution and in the solid state. |
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