| 氧化铅在氨基甲酸乙酯与乙醇合成碳酸二乙酯反应中的催化作用 |
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| 引用本文： | 郭莲,赵新强,安华良,王延吉.氧化铅在氨基甲酸乙酯与乙醇合成碳酸二乙酯反应中的催化作用[J].催化学报,2012(4):595-600. |
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| 作者姓名： | 郭莲 赵新强 安华良 王延吉 |
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| 作者单位： | 河北工业大学绿色化工与高效节能河北省重点实验室 |
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| 基金项目： | 973计划前期研究专项(2010CB234602);国家自然科学基金(20976035,21076059);河北省自然科学基金(B2010000019)~~ |
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| 摘 要： | 研究了氧化铅在氨基甲酸乙酯(EC)与乙醇反应合成碳酸二乙酯(DEC)中的催化作用.结果表明,氧化铅具有很好的稳定性,重复使用5次,其催化活性无明显下降.回收的催化剂为立方晶相金属Pb和斜方晶相PbO2的混合物,结合反应结果可认为,该混合物为反应的活性组分.结果还发现,PbO与DEC反应是PbO被还原为Pb的主要原因.
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| 关 键 词： | 碳酸二乙酯 氨基甲酸乙酯 氧化铅 乙醇 尿素 |
Catalysis by Lead Oxide for Diethyl Carbonate Synthesis from Ethyl Carbamate and Ethanol |
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| GUO Lian,ZHAO Xinqiang,AN Hualiang,WANG Yanji.Catalysis by Lead Oxide for Diethyl Carbonate Synthesis from Ethyl Carbamate and Ethanol[J].Chinese Journal of Catalysis,2012(4):595-600. |
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| Authors: | GUO Lian ZHAO Xinqiang AN Hualiang WANG Yanji |
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| Institution: | Hebei Provincial Key Lab of Green Chemical Technology and High Efficient Energy Saving,Hebei University of Technology,Tianjin 300130,China |
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| Abstract: | The catalysis by lead oxide in the reaction of ethyl carbamate(EC) with ethanol to form diethyl carbonate(DEC) was studied.The lead oxide catalyst exhibited an excellent stability,which could be reused five times without a significant loss in catalytic activity.X-Ray powder diffraction analysis showed that the recovered catalyst was a mixture of cubic metal Pb and orthorhombic PbO 2,with the latter shown to be the real active component for the synthesis of DEC.Verification experiments showed that the reaction between DEC and PbO was the main reason for the reduction of PbO to metal Pb. |
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| Keywords: | diethyl carbonate ethyl carbamate lead oxide ethanol urea |
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