Certification by the Karl Fischer method of the water content in SRM 2890, Water Saturated 1-Octanol, and the analysis of associated interlaboratory bias in the measurement process |
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| Authors: | S A Margolis Mark Levenson |
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| Institution: | National Institute of Standards and Technology, Analytical Chemistry Division, Stop 8392, Gaithersburg, MD 20899-8392, USA e-mail: sam.margolis@nist.gov, US
National Institute of Standards and Technology, Statistical Engineering Division, NIST, Gaithersburg, MD 20899-8392, USA, US
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| Abstract: | The calibration of Karl Fischer instruments and reagents and the compensation for instrumental bias are essential to the accurate measurement of trace levels of water in organic and inorganic chemicals. A stable, non-hygroscopic standard, Water Saturated Octanol, which is compatible with the Karl Fischer reagents, has been prepared. This material, Standard Reference Material (SRM) 2890, is homogeneous and is certified to contain 39.24 ± 0.85 mg water/mL (expanded uncertainty) of solution (47.3 ± 1.0 mg water/g solution, expanded uncertainty) at 21.5?°C. The solubility of water in 1-octanol has been shown to be nearly constant between 10?°C and 30?°C (i.e., within 1% of the value at 21.5?°C). The results of an interlaboratory comparison exercise illustrate the utility of SRM 2890 in assessing the accuracy and bias of Karl Fischer instruments and measurements. |
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