Relative rate constants of reactions of alkyl radicals of methacrylates and acrylates with oxygen and stable nitroxyl radicals |
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| Authors: | E. M. Pliss A. L. Aleksandrov |
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| Affiliation: | (1) Department of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka;(2) Yaroslavl Polytechnic Institute, USSR |
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| Abstract: | Conclusions In methacrylates and acrylates undergoing oxidation, stable nitroxyl radicals react with the alkyl radicals of the monomers. The relative rate constants of the reactions of and O2 with alkyl radicals for the different esters range from 0.36 to 5.20.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 753–756, April, 1977.We thank V. A. Golubev for providing the stable nitroxyl radicals. |
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