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新型的承载双金属氰化物络合催化剂
引用本文:于剑昆.新型的承载双金属氰化物络合催化剂[J].广州化学,2004,29(3):47-54.
作者姓名:于剑昆
作者单位:黎明化工研究院,河南,洛阳,471001
摘    要:用双金属氰化物(DMC)络合催化剂可制得相对分子质量高、相对分子质量分布窄和不饱和度低的聚醚多元醇。为提高DMC催化剂的利用率,降低催化剂和聚醚的生产成本,国外开发了承载的DMC催化剂。它不仅可简化聚醚的后处理工艺,而且使聚醚的连续化大规模生产得以实现,因此代表了DMC催化剂的一个重要发展方向。

关 键 词:双金属氰化物(DMC)络合催化剂  承载催化剂  低不饱和度聚醚多元醇  开环聚合
文章编号:1009-220X(2004)03-0047-08
修稿时间:2003年9月13日

Novel Supported Double Metal Cyanide Complex Catalysts
YU Jian-kun.Novel Supported Double Metal Cyanide Complex Catalysts[J].Guangzhou Chemistry,2004,29(3):47-54.
Authors:YU Jian-kun
Abstract:The polyether polyols which has higher molecular weight,narrower molecular weight distribution and lower unsaturation can be prepared by using double metal cyanide (DMC) complex catalysts.In order to increase the profitability of the DMC catalysts and decrease the production cost of the DMC catalysts and polyether polyols,the supported DMC catalysts were developed at abroad.By using the supported DMC catalysts,it can not only simplify the post-treatment of the polyether polyols,but also can produce polyether polyols in continuous with large scale.Hence it represents one of the most important development direction of the DMC catalysts.
Keywords:double metal cyanide (DMC) complex catalyst  supported catalyst  low unsaturation polyether polyols  ring-opening polymerization
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