Effect of vibrational excitation on the reactivity of methyl fluoride with bromine atoms |
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Authors: | V. P. Strunin N. K. Serdyuk E. N. Chesnokov V. N. Panfilov |
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Affiliation: | (1) Institute of Chemical Kinetics and Combustion, 630090 Novosibirsk, USSR |
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Abstract: | The influence of non-equilibrium vibrational excitation of CH3F molecules on the rate of their reaction with bromine atoms has been investigated. A three-fold increace in the reaction rate has been registered at CH3F and Br2 pressures of 0.07 Torr and at 100°C. The increase is shown not to be associated with equilibrium thermal heating.
CH3F . CH3F Br2 0,07 100°C. , . |
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