Carbon-carbon bond formation employing organoiron reagents : Syntheses of lavandulol and red scale pheromone |
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Authors: | J. Celebuski M. Rosenblum |
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Affiliation: | Department of Chemistry, Brandeis University, Waltham, MA 02254, U.S.A. |
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Abstract: | Some aspects of the chemistry of (η1-allyl)Fp complexes [Fp =η5-C5H5Fe(CO)2] are briefly reviewed, especially the means available for their elaboration. The range of electrophiles which react with (η1-allyl)Fp complexes has been enlarged to include allyl iodides. Two examples of this reaction are given, the first leading to lavandulol 9, the second providing a short synthesis of the red scale pheromone (R,S-15). |
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