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| 聚(2-甲氧基-5-壬氧基)对苯乙炔的合成及其电致发光性质 | |
| 引用本文： | 王建营,李银奎,龙永福,胡文祥. 聚(2-甲氧基-5-壬氧基)对苯乙炔的合成及其电致发光性质[J]. 功能高分子学报, 2000, 13(1): 93-96 |
| 作者姓名： | 王建营 李银奎 龙永福 胡文祥 |
| 作者单位： | 1. 解放军总装备部军事医学研究所,7202信箱,北京,100101;国防科技大学材料工程与应用化学系,湖南,长沙,410073 2. 国防科技大学材料工程与应用化学系,湖南,长沙,410073 3. 解放军总装备部军事医学研究所,7202信箱,北京,100101 |
| 摘 要： | 以对甲氧基苯酚和溴代正壬烷为原料，通过醚化、氯甲基化和脱氯化氢反应得到可溶性的聚（２－甲氧基－５－壬氧基）对苯乙炔，以其为发光层装配了聚合物单层电致发光器件，研究了它的电致发光和光致发光性质；电致发光器件具有良好的稳定性，其起亮电压为７Ｖ。聚合物的结构由ＩＲ、＾１Ｈ－ＮＭＲ及ＵＶ／Ｖｉｓ光谱得到确认。 |
| 关 键 词： | 脱氯化氢反应 合成 电致发光性质 聚对苯乙炔 |
| 修稿时间： | 1999-08-20 |
Synthesis and Electroluminescence of Soluble Poly(2-methoxy-5-nonyloxy)-1,4-phenylene Vinylene |
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| WANG Jian-ying,LI Yin-kui,LONG Yong-fu,HU Wen-xiang. Synthesis and Electroluminescence of Soluble Poly(2-methoxy-5-nonyloxy)-1,4-phenylene Vinylene[J]. Journal of Functional Polymers, 2000, 13(1): 93-96 | |
| Authors: | WANG Jian-ying LI Yin-kui LONG Yong-fu HU Wen-xiang |
| Affiliation: | WANG Jian ying 1,2,LI Yin kui 2,LONG Yong fu 2,HU Wen xiang 1 |
| Abstract: | The soluble poly(2 methoxy 5 nonyloxy) p phenylene vinylene (PMONOPV) was synthesized by three steps with p methoxylphenol and CH 3(CH 2) 8Br as raw material: etherification, bischloromethylation and dehydrochlorination. A single layer polymer electroluminescent devices has been fabricated with PMONOPV as light emitting layer. The electroluminescence and photoluminescence of PMONOPV were studied. The results showed that the electroluminescent devices with low voltages(7 V) were stable . The structure of polymer is identified by UV./Vis. IR and 1 H NMR. |
| Keywords: | soluble poly(2 methoxy 5 nonyloxy) p phenylene vinylene) dehydrochlorination synthesis electroluminescence |
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