First magnetostructural study on a heterodinuclear 2,2'-bipyrimidine-bridged complex |
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| Authors: | Martínez-Lillo José Armentano Donatella De Munno Giovanni Cano Joan Lloret Francesc Julve Miguel Faus Juan |
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| Affiliation: | Departament de Química Inorgànica/Instituto de Ciencia Molecular (ICMol), Facultat de Química, Universitat de València, Avenida Dr. Moliner 50, 46100 Burjassot, València, Spain. lillo@uv.es |
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| Abstract: | The use of the [ReCl(4)(bpym)] precursor as a ligand toward the fully solvated nickel(II) metal ion affords the first example of a 2,2'-bipyrimidine-bridged Re(IV)-Ni(II) complex, [ReCl(4)(μ-bpym)NiBr(2)(H(2)O)(2)] (1), whose intramolecular ferromagnetic coupling has been substantiated from both experimental and theoretical studies. |
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