| Synthesis and Characterization of the Host-Guest NanocompositeMaterial Zeolite Y-Iron Bipyridine |
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| 引用本文： | Yan Xia JIANG, Wen Bo SONG, Ying LIU, Hong Ding XU(Department of Chemistry of Jilin University. Changchun 130023). Synthesis and Characterization of the Host-Guest NanocompositeMaterial Zeolite Y-Iron Bipyridine[J]. 中国化学快报, 1999, 0(6) |
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| 作者姓名： | Yan Xia JIANG Wen Bo SONG Ying LIU Hong Ding XU(Department of Chemistry of Jilin University. Changchun 130023) |
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| 摘 要： | Zeoliteshavethedefinedcrystallinestructureswiththechannelsorcagesofnanoscaledimensions.Thesechannelsorcagesofzeolitescanoffertheloadingsitestoselfassembleandstabilizetheentrappedguestwithinthezeolitesthatcanbeusedforusefulmatrixestoproducenanoguestsmaterialsl.Becausethiskindofmaterialsshowedsomespecialproperty=,ithasarousedmuchinterest3.Anewfieldofinvestigationfortheentrappedmetalcomplexeshasbeendevelopedinelectro-assistedcatalysisoforganicreaction'.Atpresent,therearethreeapproachestotheprepar…
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Synthesis and Characterization of the Host-Guest Nanocomposite Material Zeolite Y-Iron Bipyridine |
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| Yan Xia JIANG, Wen Bo SONG, Ying LIU, Hong Ding XU. Synthesis and Characterization of the Host-Guest Nanocomposite Material Zeolite Y-Iron Bipyridine[J]. Chinese Chemical Letters, 1999, 0(6) |
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| Authors: | Yan Xia JIANG Wen Bo SONG Ying LIU Hong Ding XU |
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| Affiliation: | Department of Chemistry of Jilin University. Changchun 130023 |
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| Abstract: | This paper reports the synthesis of host-guest nanocomposite material [Fe(bpy)3](2 )Y (where bpy=2.2-bipyridine) using the flexible ligand method. X-ray diffraction analysis. adsorption technique. and cyclic voltammetry were used to characterize the material. The results show that [Fe(bpy)3](2 ) has been entrapped in the supercage of zeolite. its electron transfer is realized by electron hopping of [Fe(bpy)3](2 ) within the supercage of zeolite. |
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| Keywords: | Host-guest nanocomposite material zeolite Y iron bipyridine intrazeolite electron transfer |
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