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Hydrogenation of ethyl acetate over supported rhenium catalysts
Authors:M A Ryashentseva  V I Avaev
Institution:(1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation
Abstract:Re/Sibunite is a more active and selective catalyst for hydrogenation of ethyl acetate to ethanol under elevated temperatures and hydrogen pressures than Re/θ-Al2O3 and Re/γ-Al2O3. The activity of the catalyst is increased on replacing NH4ReO4 with HReO4 and treatment of the support with a 13% solution of HNO3. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1006–1008, May, 1999.
Keywords:supported Re catalysts  ethyl acetate  ethanol  diethyl ether  hydrogenation
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