Formation and cleavage of C-H, C-C, and C-O bonds of ortho-methyl-substituted anisoles by late transition metals |
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| Authors: | Lara Patricia Paneque Margarita Poveda Manuel L Salazar Verónica Santos Laura L Carmona Ernesto |
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| Institution: | Instituto de Investigaciones Químicas, Departamento de Química Inorganica, CSIC, Universidad de Sevilla, Avda. Américo Vespucio no 49, 41092 Sevilla, Spain. |
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| Abstract: | 2,6-Dimethyl-substituted anisoles can be converted into the corresponding 2-ethyl-6-methylphenols in a several-step reaction mediated by a TpMe2Ir(III) complex; use of the 13C-enriched anisoles, ArO13CH3, shows that the 13C label distributes across the two ethyl sites with a preference for the terminal position. |
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