Electron transfer-initiated Diels-Alder cycloadditions of 2'-hydroxychalcones |
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| Authors: | Cong Huan Ledbetter Dustin Rowe Gerard T Caradonna John P Porco John A |
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| Institution: | Department of Chemistry and Center for Chemical Methodology and Library Development, Boston University, Boston, Massachusetts 02215, USA. |
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| Abstract: | An efficient approach to cyclohexenyl chalcones employing highly electron rich 2'-hydroxychalcone dienophiles via electron transfer-initiated Diels-Alder cycloaddition is described. Using the methodology, the total synthesis of nicolaiodesin C has been accomplished. |
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