Mathematical Models for Waxy Crude Oils

In this paper we review a series of mathematical models formulated for the flow of waxy crude oils, that is, of mineral oils with a high content of paraffinic hydrocarbons (with the generic name of waxes) which may be dissolved or segregated as solid crystals at sufficiently low temperatures. The flow takes place in a laboratory test loop. The crystals have a tendency to form aggregates, producing a gel-like structure. The resulting product can be modeled as a Bingham fluid, but its rheological parameters (yield stress and viscosity) depend on the amount and state of the segregated phase, whose evolution is in turn influenced by the flow. Of course temperature plays a key role. Wax can form a solid deposit at the pipe wall, reducing the pipe radius and this phenomenon is also taken into account. The models presented have a different degree of complexity, depending on which phenomena they include. In presenting each of them we discuss their expected range of validity.