Synthesis and Crystal Structure of 3-Methyl-4-phenyl-5-(2-pyridyl)-1,2,4-triazole |
| |
| Authors: | Chunyi Liu Zuoxiang Wang Hailian Xiao Yan Lan Xiaomin Li Songpei Wang Jie Tang Zhengping Chen |
| |
| Institution: | (1) The Key Laboratory of Nuclear Medicine, Ministry of Health P.R. China, Jiangsu Institute of Nuclear Medicine, 20 Qianrong Road, 214063 Wuxi, People’s Republic of China;(2) Department of Chemistry & Chemical Engineering, Southeast University, 210096 Nanjing, People’s Republic of China;(3) New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science & Technology, 266042 Qingdao, People’s Republic of China; |
| |
| Abstract: | Abstract The title compound, 3-methyl-4-phenyl-5-(2-pyridyl)-1,2,4-triazole was synthesized by reaction of diphenylphosphazoanilide
with N-acetyl-N′-(2-pyridoyl)hydrazine. Crystals suitable for X-ray analysis were obtained from a mixed solution of water and ethanol in
a one-to-one volume ratio. The crystal is orthorhombic, space group P212121 with crystallographic parameters: a = 19.414(4) Å, b = 17.172(3) Å, c = 7.4850(15) Å, β = 90.00°, μ = 0.079 mm−1, V = 2495.3(8) Å3, Z = 8, Dc = 1.258 g/cm3, F(000) = 992, T = 295(2) K. The X-ray results showed that in the crystal structure of the title compound, the 1,2,4-triazole, pyridine and
benzene rings are not coplanar. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
