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alpha-thiocyanation of carbonyl and beta-dicarbonyl compounds using (dichloroiodo)benzene-lead(II) thiocyanate
Authors:Prakash O  Kaur H  Batra H  Rani N  Singh S P  Moriarty R M
Affiliation:Department of Chemistry, Kurukshetra University, Kurukshetra 136119, Haryana, India. chem@granth.kuk.ernet.in
Abstract:The combination reagent (dichloroiodo)benzene and lead(II) thiocyanate in dichloromethane effects oxidation of various enol silyl ethers, ketene silyl acetals, and beta-dicarbonyl compounds, thereby providing an efficient and convenient method for alpha-thiocyanation of carbonyl and beta-dicarbonyl compounds.
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