Relation of chemical structure to reactivity in complete oxidation on oxide contact catalysts for open-chain hydrocarbons |
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| Authors: | G I Golodets Yu I Pyatnitskii V V Goncharuk |
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| Institution: | (1) Pisarzhevskii Institute of Physical Chemistry, AS UkrSSR, Kiev |
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| Abstract: | It is shown that the relative reactivities of alkanes, alkenes, alkynes, and cyclopropane in complete oxidation decreases with increase in the energy of the bond broken in the rate-limiting step: for alkanes from ethane upwards this is a C-C bond, for unsaturated hydrocarbons it is the  -type C-C bond, and for methane it is a C-H bond. |
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