| 共沉淀CuO-ZrO2复合氧化物分散态结构研究 |
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| 引用本文： | 杨鹏程,蔡小海,谢有畅. 共沉淀CuO-ZrO2复合氧化物分散态结构研究[J]. 物理化学学报, 2003, 19(8): 714-717. DOI: 10.3866/PKU.WHXB20030808 |
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| 作者姓名： | 杨鹏程 蔡小海 谢有畅 |
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| 作者单位： | College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 |
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| 基金项目： | 国家自然科学基金(29733080、29773002)~~ |
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| 摘 要： | 用XRD、EXAFS、XPS表征了共沉淀法制备的CuO-ZrO2复合氧化物的分散态结构. 500 ℃焙烧的样品在一定组成范围内形成大体均匀的无定形态固溶体. CuO含量超过其在ZrO2中溶解度时，多余的CuO以CuO晶体形式存在；当ZrO2含量超过其在CuO中溶解度时，多余的ZrO2以四方相ZrO2晶体形式存在.焙烧温度达到800 ℃时，样品由单斜相ZrO2和CuO晶体组成.
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| 关 键 词： | CuO ZrO2 XRD EXAFS 固溶体 |
| 收稿时间： | 2003-01-20 |
| 修稿时间： | 2003-03-24 |
Studies on the Dispersion Structure of Co-precipitated CuO-ZrO2 Mixed Oxides |
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| Yang Peng-Cheng Cai Xiao-Hai Xie You-Chang. Studies on the Dispersion Structure of Co-precipitated CuO-ZrO2 Mixed Oxides[J]. Acta Physico-Chimica Sinica, 2003, 19(8): 714-717. DOI: 10.3866/PKU.WHXB20030808 |
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| Authors: | Yang Peng-Cheng Cai Xiao-Hai Xie You-Chang |
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| Affiliation: | College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 |
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| Abstract: | Co-precipitated CuO-ZrO2 mixed oxides were characterized by XRD,EXAFS, XPS methods. For the samples calcined at 500 ℃, amorphous solid solution forms between CuO and ZrO2 in the co-precipitated samples. The extra CuO crystal exists if CuO is more than its solubility in ZrO2, and extra tetragonal ZrO2 crystal exists if ZrO2 content is more than its solubility in CuO. After calcined at 800 ℃, the samples compose of monoclinic ZrO2 and CuO crystals. |
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| Keywords: | CuO ZrO2 XRD EXAFS Solid solution |
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