Isotope Shifts in the TiO B-X (1-0) Band |
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Authors: | C AmiotP Luc R Vetter |
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Institution: | Laboratoire Aimé Cotton11Laboratoire Aimé Cotton is in association with Université Paris Sud, Orsay., Bât 505, Campus d'Orsay, Orsay Cedex, 91405, France |
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Abstract: | The absorption spectrum of the B3Π-X3Δ (1-0) band of the TiO molecule has been studied at sub-Doppler resolution by crossing an effusive beam of TiO with a cw tunable laser beam and by collecting the induced fluorescence light. The five bands involving the 46Ti, 47Ti, 48Ti, 49Ti, and 50Ti isotopic species have been observed and interpreted. A simultaneous analysis of the five isotopic data leads to accurate molecular constants and energy levels for the B3Π electronic state. |
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Keywords: | laser spectroscopy |
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