Cyclization of citronellal in a supercritical solvent in a flow reactor in the presence of Al2O3 |
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| Authors: | V I Anikeev I V Il’ina K P Volcho N F Salakhutdinov |
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| Institution: | 1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia
2. Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia
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| Abstract: | The reactivity of citronellal under supercritical solvent conditions in a flow reactor in the presence of Al2O3 is examined. It is shown that at 160°C, the main transformation product of citronellal is isopulegol, and when the temperature is increased to 190°C, they are monoterpenes with a para-menthane framework and myrcene. |
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