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Conducting polyaniline/multi-wall carbon nanotubes composite paints on low carbon steel for corrosion protection: electrochemical investigations
Authors:Pravin P. Deshpande  Sanket S. Vathare  Shashikant T. Vagge  Elena Tomšík  Jaroslav Stejskal
Affiliation:1273. Department of Metallurgy and Materials Science, College of Engineering, Shivajinagar, 411005, Pune, India
2273. Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovsky Sq. 2, 162 06, Prague 6, Czech Republic
Abstract:The coaxial coating of multi-wall carbon nanotubes (MWCNT) with poly(aniline) (PANI) was synthesised and a paint was prepared containing conducting PANI-MWCNT composite. The corrosion protection performance was assessed by open circuit potential measurements, potentiodynamic polarisation, and electrochemical impedance spectroscopy. The corrosion rate of low-carbon steel coated with 1.5 mass % of PANI-MWCNT-based paint in 3.5 mass % sodium chloride solution was found to be 0.037 mm y?1, about 5.2 times lower than that of unpainted low-carbon steel and 3.6 times lower than that of epoxy painted steel.
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