Liquid phase oxidation of acrolein catalyzed by Co and Mo complexes |
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Authors: | J Haber A Marchut T Modnicka J Potowicz and J J Ziokowski |
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Institution: | (1) Research Laboratories of Catalysis and Surface Chemistry, Polish Academy of Sciences, Kraków, Poland;(2) Institute of Chemistry, University of Wroc aw, Wroc aw, Poland |
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Abstract: | Liquid phase catalytic oxidation of acrolein in the presence of Co(III) and Mo(VI) complexes was investigated. The addition of a Mo(VI) complex was found to accelerate the reaction at higher, and retard it at lower, Co(III) concentrations.
![Bcy](/content/728267t5023297nw/xxlarge1041.gif) ![ycy](/content/728267t5023297nw/xxlarge1099.gif) ![lcy](/content/728267t5023297nw/xxlarge1083.gif) ![icy](/content/728267t5023297nw/xxlarge1080.gif) ![scy](/content/728267t5023297nw/xxlarge1089.gif) ![scy](/content/728267t5023297nw/xxlarge1089.gif) ![lcy](/content/728267t5023297nw/xxlarge1083.gif) ![iecy](/content/728267t5023297nw/xxlarge1077.gif) ![dcy](/content/728267t5023297nw/xxlarge1076.gif) ![ocy](/content/728267t5023297nw/xxlarge1086.gif) ![vcy](/content/728267t5023297nw/xxlarge1074.gif) ![acy](/content/728267t5023297nw/xxlarge1072.gif) ![ncy](/content/728267t5023297nw/xxlarge1085.gif) ![zhcy](/content/728267t5023297nw/xxlarge1078.gif) ![icy](/content/728267t5023297nw/xxlarge1080.gif) ![dcy](/content/728267t5023297nw/xxlarge1076.gif) ![kcy](/content/728267t5023297nw/xxlarge1082.gif) ![ocy](/content/728267t5023297nw/xxlarge1086.gif) ![fcy](/content/728267t5023297nw/xxlarge1092.gif) ![acy](/content/728267t5023297nw/xxlarge1072.gif) ![zcy](/content/728267t5023297nw/xxlarge1079.gif) ![ncy](/content/728267t5023297nw/xxlarge1085.gif) ![ocy](/content/728267t5023297nw/xxlarge1086.gif) ![kcy](/content/728267t5023297nw/xxlarge1082.gif) ![acy](/content/728267t5023297nw/xxlarge1072.gif) ![tcy](/content/728267t5023297nw/xxlarge1090.gif) ![acy](/content/728267t5023297nw/xxlarge1072.gif) ![lcy](/content/728267t5023297nw/xxlarge1083.gif) ![icy](/content/728267t5023297nw/xxlarge1080.gif) ![tcy](/content/728267t5023297nw/xxlarge1090.gif) ![icy](/content/728267t5023297nw/xxlarge1080.gif) ![chcy](/content/728267t5023297nw/xxlarge1095.gif) ![iecy](/content/728267t5023297nw/xxlarge1077.gif) ![scy](/content/728267t5023297nw/xxlarge1089.gif) ![kcy](/content/728267t5023297nw/xxlarge1082.gif) ![ocy](/content/728267t5023297nw/xxlarge1086.gif) ![ocy](/content/728267t5023297nw/xxlarge1086.gif) ![kcy](/content/728267t5023297nw/xxlarge1082.gif) ![icy](/content/728267t5023297nw/xxlarge1080.gif) ![scy](/content/728267t5023297nw/xxlarge1089.gif) ![lcy](/content/728267t5023297nw/xxlarge1083.gif) ![iecy](/content/728267t5023297nw/xxlarge1077.gif) ![ncy](/content/728267t5023297nw/xxlarge1085.gif) ![icy](/content/728267t5023297nw/xxlarge1080.gif) ![acy](/content/728267t5023297nw/xxlarge1072.gif) ![kcy](/content/728267t5023297nw/xxlarge1082.gif) ![rcy](/content/728267t5023297nw/xxlarge1088.gif) ![ocy](/content/728267t5023297nw/xxlarge1086.gif) ![lcy](/content/728267t5023297nw/xxlarge1083.gif) ![iecy](/content/728267t5023297nw/xxlarge1077.gif) ![icy](/content/728267t5023297nw/xxlarge1080.gif) ![ncy](/content/728267t5023297nw/xxlarge1085.gif) ![pcy](/content/728267t5023297nw/xxlarge1087.gif) ![rcy](/content/728267t5023297nw/xxlarge1088.gif) ![icy](/content/728267t5023297nw/xxlarge1080.gif) ![scy](/content/728267t5023297nw/xxlarge1089.gif) ![ucy](/content/728267t5023297nw/xxlarge1091.gif) ![tcy](/content/728267t5023297nw/xxlarge1090.gif) ![scy](/content/728267t5023297nw/xxlarge1089.gif) ![tcy](/content/728267t5023297nw/xxlarge1090.gif) ![vcy](/content/728267t5023297nw/xxlarge1074.gif) ![icy](/content/728267t5023297nw/xxlarge1080.gif) ![kcy](/content/728267t5023297nw/xxlarge1082.gif) ![ocy](/content/728267t5023297nw/xxlarge1086.gif) ![mcy](/content/728267t5023297nw/xxlarge1084.gif) ![pcy](/content/728267t5023297nw/xxlarge1087.gif) ![lcy](/content/728267t5023297nw/xxlarge1083.gif) ![iecy](/content/728267t5023297nw/xxlarge1077.gif) ![kcy](/content/728267t5023297nw/xxlarge1082.gif) ![scy](/content/728267t5023297nw/xxlarge1089.gif) ![ocy](/content/728267t5023297nw/xxlarge1086.gif) Co(III) Mo(VI). ![Dcy](/content/728267t5023297nw/xxlarge1044.gif) ![ocy](/content/728267t5023297nw/xxlarge1086.gif) ![bcy](/content/728267t5023297nw/xxlarge1073.gif) ![acy](/content/728267t5023297nw/xxlarge1072.gif) ![vcy](/content/728267t5023297nw/xxlarge1074.gif) ![lcy](/content/728267t5023297nw/xxlarge1083.gif) ![iecy](/content/728267t5023297nw/xxlarge1077.gif) ![ncy](/content/728267t5023297nw/xxlarge1085.gif) ![icy](/content/728267t5023297nw/xxlarge1080.gif) ![kcy](/content/728267t5023297nw/xxlarge1082.gif) ![ocy](/content/728267t5023297nw/xxlarge1086.gif) ![mcy](/content/728267t5023297nw/xxlarge1084.gif) ![pcy](/content/728267t5023297nw/xxlarge1087.gif) ![lcy](/content/728267t5023297nw/xxlarge1083.gif) ![iecy](/content/728267t5023297nw/xxlarge1077.gif) ![kcy](/content/728267t5023297nw/xxlarge1082.gif) ![scy](/content/728267t5023297nw/xxlarge1089.gif) Mo(VI) ![ucy](/content/728267t5023297nw/xxlarge1091.gif) ![scy](/content/728267t5023297nw/xxlarge1089.gif) ![kcy](/content/728267t5023297nw/xxlarge1082.gif) ![ocy](/content/728267t5023297nw/xxlarge1086.gif) ![rcy](/content/728267t5023297nw/xxlarge1088.gif) ![yacy](/content/728267t5023297nw/xxlarge1103.gif) ![iecy](/content/728267t5023297nw/xxlarge1077.gif) ![rcy](/content/728267t5023297nw/xxlarge1088.gif) ![iecy](/content/728267t5023297nw/xxlarge1077.gif) ![acy](/content/728267t5023297nw/xxlarge1072.gif) ![kcy](/content/728267t5023297nw/xxlarge1082.gif) ![tscy](/content/728267t5023297nw/xxlarge1094.gif) ![icy](/content/728267t5023297nw/xxlarge1080.gif) ![pcy](/content/728267t5023297nw/xxlarge1087.gif) ![rcy](/content/728267t5023297nw/xxlarge1088.gif) ![vcy](/content/728267t5023297nw/xxlarge1074.gif) ![ycy](/content/728267t5023297nw/xxlarge1099.gif) ![scy](/content/728267t5023297nw/xxlarge1089.gif) ![ocy](/content/728267t5023297nw/xxlarge1086.gif) ![kcy](/content/728267t5023297nw/xxlarge1082.gif) ![icy](/content/728267t5023297nw/xxlarge1080.gif) ![kcy](/content/728267t5023297nw/xxlarge1082.gif) ![ocy](/content/728267t5023297nw/xxlarge1086.gif) ![ncy](/content/728267t5023297nw/xxlarge1085.gif) ![tscy](/content/728267t5023297nw/xxlarge1094.gif) ![iecy](/content/728267t5023297nw/xxlarge1077.gif) ![ncy](/content/728267t5023297nw/xxlarge1085.gif) ![tcy](/content/728267t5023297nw/xxlarge1090.gif) ![rcy](/content/728267t5023297nw/xxlarge1088.gif) ![acy](/content/728267t5023297nw/xxlarge1072.gif) ![tscy](/content/728267t5023297nw/xxlarge1094.gif) ![icy](/content/728267t5023297nw/xxlarge1080.gif) ![yacy](/content/728267t5023297nw/xxlarge1103.gif) Co(III) ![ucy](/content/728267t5023297nw/xxlarge1091.gif) ![mcy](/content/728267t5023297nw/xxlarge1084.gif) ![iecy](/content/728267t5023297nw/xxlarge1077.gif) ![ncy](/content/728267t5023297nw/xxlarge1085.gif) ![softcy](/content/728267t5023297nw/xxlarge1100.gif) ![shcy](/content/728267t5023297nw/xxlarge1096.gif) ![acy](/content/728267t5023297nw/xxlarge1072.gif) ![iecy](/content/728267t5023297nw/xxlarge1077.gif) ![pcy](/content/728267t5023297nw/xxlarge1087.gif) ![rcy](/content/728267t5023297nw/xxlarge1088.gif) ![ncy](/content/728267t5023297nw/xxlarge1085.gif) ![icy](/content/728267t5023297nw/xxlarge1080.gif) ![zcy](/content/728267t5023297nw/xxlarge1079.gif) ![kcy](/content/728267t5023297nw/xxlarge1082.gif) ![icy](/content/728267t5023297nw/xxlarge1080.gif) ![kcy](/content/728267t5023297nw/xxlarge1082.gif) ![ocy](/content/728267t5023297nw/xxlarge1086.gif) ![ncy](/content/728267t5023297nw/xxlarge1085.gif) ![tscy](/content/728267t5023297nw/xxlarge1094.gif) ![iecy](/content/728267t5023297nw/xxlarge1077.gif) ![ncy](/content/728267t5023297nw/xxlarge1085.gif) ![tcy](/content/728267t5023297nw/xxlarge1090.gif) ![rcy](/content/728267t5023297nw/xxlarge1088.gif) ![acy](/content/728267t5023297nw/xxlarge1072.gif) ![tscy](/content/728267t5023297nw/xxlarge1094.gif) ![icy](/content/728267t5023297nw/xxlarge1080.gif) ![yacy](/content/728267t5023297nw/xxlarge1103.gif) Co(III).
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