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On the rotational partition function for tetrahedral molecules |
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| Authors: | K Fox |
| Institution: | Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California 91103, USA Department of Physics and Astronomy, The University of Tennessee, Knoxville, Tennessee 37916, USA |
| Abstract: | A rigorous calculation of the quantum-mechanical rotational partition function for tetrahedral XY4 molecules yields Qr = ( -/4), where IY is the spin of the Y nucleus, and ≡ Bhc/kT. This result is accurate to 1 per cent or better for all values of B and T such that < |
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