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| Fe(CO)5多光子解离和电离动力学 | |
| 引用本文： | 李书涛,韩景诚,刘厚祥,李昭临,吴存恺,史济良,李方琳.Fe(CO)5多光子解离和电离动力学[J].物理化学学报,1988,4(6):669-672. |
| 作者姓名： | 李书涛 韩景诚 刘厚祥 李昭临 吴存恺 史济良 李方琳 |
| 作者单位： | Laboratory of Laser Spectroscopy; Anhui Institute of Optics and Fine Mechanics; Academia Sinica;Shanghai Institute of Organic Chemistry; Academia Sinica |
| 摘 要： | |
| 收稿时间： | 1986-07-26 |
| 修稿时间： | 1988-06-07 |
MULTIPHOTON DISSOCIATION-IONIZATION DYNAMICS OF Fe(CO)5 |
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| Li Shutao,Han Jingcheng,Liu Houxiang,Li Zhaolin,Wu Cunkai, Shi Jiliang,Li Fanglin.MULTIPHOTON DISSOCIATION-IONIZATION DYNAMICS OF Fe(CO)5[J].Acta Physico-Chimica Sinica,1988,4(6):669-672. |
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| Authors: | Li Shutao Han Jingcheng Liu Houxiang Li Zhaolin Wu Cunkai Shi Jiliang Li Fanglin |
| Institution: | Laboratory of Laser Spectroscopy; Anhui Institute of Optics and Fine Mechanics; Academia Sinica;Shanghai Institute of Organic Chemistry; Academia Sinica |
| Abstract: | Multiphoton dissociation-ionization dynamics of Fe(CO)_5 were studied mass spectrometrically with a molecular beam and XeCl excimer laser. The results show that Fe(CO)_n~+ (n= 1,2,… ,5) and Fe_2(CO)_4~+ ions are formed mainly via ion-molecule reaction between Fe~+ and Fe(CO)_5 and dissociation following. A “ladder” model of Fe(CO)_5 photodissociation is presented in the paper. |
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