Ionic radii for Group 1 halide crystals and ion-pairs |
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| Authors: | Collin Richard J Smith Barry C |
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| Affiliation: | Cranleigh School, Cranleigh, Surrey, GU6 8QQ, UK. |
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| Abstract: | Internuclear separations calculated from empirical soft-sphere radii for seventeen crystalline Group 1 halides with rock-salt structures and from empirical hovering-sphere radii for fourteen gaseous Group 1 halide ion-pairs agree well with experimental measurements. Two lithium and four fluoride ion-pairs appear to be anomalous. Soft-sphere ionic radii are compared with atomic radii of noble gases. |
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