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烟气中二氧化硫及三氧化硫测定方法的研究
引用本文:黄梅芬,沈十林.烟气中二氧化硫及三氧化硫测定方法的研究[J].理化检验(化学分册),1994,30(3):10-12.
作者姓名:黄梅芬  沈十林
作者单位:上海材料研究所 200437
摘    要:本文采用过氧化氢-氯化钡-钍试剂法以及80%异丙醇-氯化钡-钍试剂法分别测定了烟气中的二氧化硫及三氧化硫质量浓度,并对该方法的灵敏度、准确度以及各种影响因素进行了研究分析.本方法简单、快速、准确、便于现场监测控制.

关 键 词:二氧化硫  三氧化硫  烟气

DETERMINATION OF SULFUR DIOXIDE AND SULFUR TRIOXIDE IN STACK GASES
Huang Meifen and Shen Shilin.DETERMINATION OF SULFUR DIOXIDE AND SULFUR TRIOXIDE IN STACK GASES[J].Physical Testing and Chemical Analysis Part B:Chemical Analgsis,1994,30(3):10-12.
Authors:Huang Meifen and Shen Shilin
Abstract:A method for the determination of sulfur dioxide and sulfur trioxide in stack gases is reported in this paper and optimum conditions have been discussed thoroughly. Sulfur dioxide is absorbed quantitatively in a solution of 3% hydrogen peroxide and sulfur trioxide absorbed guantitatively in 80% isopropyl alcohol solution,which inhibits oxidation of sulfur dioxide. Then the sulfate was titrated with standard barium chloride solution in 80% isopropyl alcohol using Thorin as indicator. The proposed method is simple and the titration is rapid. It is convenient to determine and control sulfur dioxide and sulfur trioxide insite.
Keywords:Sulfur dioxide  Sulfur trioxide  Stack gas  
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