Influence of increasing zinc contents in brass in the early stages of corrosion investigated by in-situ TM-AFM and SIMS |
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Authors: | Kleber Christoph Rosner Martin Hutter Herbert Schreiner Manfred |
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Institution: | Institute of Science and Technologies in Art, Academy of Fine Arts, Schillerplatz 3, 1010 Vienna, Austria. chkleber@iac.tuwien.ac.at |
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Abstract: | In-situ tapping mode atomic force microscopy (TM-AFM), a powerful, high-resolution imaging technique for determining the structure of surfaces and ex-situ secondary ion mass spectroscopy (SIMS), a multielement, high-depth-resolution method, were used to examine the influence of increasing zinc contents in brass in the early stages of corrosion. Four different samples (pure Cu, pure Zn, Cu/Zn=90/10 wt% and Cu/Zn=70/30 wt%) were studied in order to determine their chemical behaviour under various atmospheric conditions. The in-situ TM-AFM investigations were carried out in synthetic air with 60% relative humidity (RH) and 80% RH with 250 ppb SO(2). The samples for the ex-situ SIMS experiments were weathered over a period of 60 h in 80% RH and 250 ppb SO(2). The in-situ TM-AFM investigations have shown that an increasing Zn content in brass increases the corrosion rate. |
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