Unique diketopiperazine dimers from the insect pathogenic fungus Verticillium hemipterigenum BCC 1449 |
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Authors: | Isaka Masahiko Palasarn Somporn Rachtawee Pranee Vimuttipong Saovaluk Kongsaeree Palangpon |
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Institution: | National Center for Genetic Engineering and Biotechnology (BIOTEC), Thailand Science Park, 113 Phaholyothin Road, Klong Luang, Pathumthani 12120, Thailand. isaka@biotec.or.th |
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Abstract: | structure: see text]. Vertihemiptellides A (1) and B (2), unique diketopiperazine dimers, were isolated from the insect pathogenic fungus Verticillium hemipterigenum BCC 1449. Structures of these compounds were elucidated by NMR and mass spectral analysis, and the stereochemistry of 1 was determined by X-ray crystallography. The absolute stereochemistry of bisdethiodi(methylthio)-1-demethylhyalodendrin (3), previously isolated from the same fungus, was revised to the (3R,6R) configuration. |
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