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Organogold clusters protected by phenylacetylene
Authors:Maity Prasenjit  Tsunoyama Hironori  Yamauchi Miho  Xie Songhai  Tsukuda Tatsuya
Institution:Catalysis Research Center, Hokkaido University, Nishi 10, Kita 21, Sapporo 001-0021, Japan.
Abstract:A new class of monolayer-protected Au clusters with Au-C covalent bonds (organogold clusters) was synthesized by ligating phenylacetylene (PhC≡CH) to PVP-stabilized Au clusters. Matrix-assisted laser desorption ionization mass spectrometry revealed for the first time a series of stable compositions of the organogold (Au:C(2)Ph) clusters.
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