Thermodynamic characteristics of ionic association in dimethylformamide solutions of barium iodide and zinc and lantane chlorides |
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| Authors: | T V Nikitina and S N Solov’ev |
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| Institution: | (1) Department of Physical Chemistry, University of Ł?dź, Pomorska 165, 90-236 Ł?dź, Poland |
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| Abstract: | Enthalpies of electrolyte transfer and differences between enthalpies of anions transfer from water to mixed solvent were
defined on the basis of results from our own measurements of dissolution enthalpies of potassium acetate in mixed solvents
acetonitrile-water and dimethylformamide-water of different composition, and of the literature data on dissolution enthalpies
of other electrolytes in the same mixed solvents. These values are discussed with the aim of establishing the principles of
solvatation for different anions in the studied mixed solvents. |
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