Mechanochemical processes with the reaction-induced mechanical activation. Chemo-mechanochemical effect |
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Authors: | V. V. Boldyrev |
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Affiliation: | 1.Institute of Solid-State Chemistry and Mechanochemistry,Siberian Branch of Russian Academy of Sciences,Novosibirsk,Russian Federation;2.Novosibirsk State University,Novosibirsk,Russian Federation |
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Abstract: | The review addresses the special case of mechanical activation of solid-state chemical reactions when the stress field, strain, and defects in crystals are induced by the chemical reaction itself rather than by the external mechanical impact (chemo-mechanochemical (CMC) effect). This review presents the analysis and state-of-the-art of research activities in this area. Different cases of the CMC effect in homogeneous and heterogeneous systems are considered: with or without changes in the chemical composition, with or without formation of solid products, etc. |
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