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Bimetallic NiFe2O4 synthesized via confined carburization in NiFe-MOFs for efficient oxygen evolution reaction
Authors:Zhiqiang Fang  Zhaomin Hao  Qingsong Dong  Yong Cui
Affiliation:1.Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering,Henan University,Henan,China;2.Division of Materials for Special Environments, Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research,Chinese Academy of Sciences,Shenyang,China
Abstract:Transition metal oxides that derived from metal–organic framework (MOF) precursor have intensively received attention because of their numerous electrochemical applications. Bimetallic Ni-Fe oxides have been rarely reported on the basis of MOF-related strategy. Herein, a bimetallic NiFe2O4 was successfully synthesized via confined carburization in NiFe-MOF precursors and characterized by XRD, XPS, SEM, and TEM. After conducting an investigation of oxygen evolution reaction (OER), the as-synthesized NiFe2O4 material exhibited good catalytic efficiency and high stability and durability in alkaline media. The as-synthesized NiFe2O4 material would promote the development of MOFs in non-noble-metal OER catalyst.
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