| 铁系元素冠醚配合物的研究——Ⅱ. 铁系氯化物与4''-碘苯并-15-冠-5固态配合物的合成与性质 |
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| 引用本文： | 卢爱茹,张联祥,张卫锴,缪荣生,王流芳,晏国洪. 铁系元素冠醚配合物的研究——Ⅱ. 铁系氯化物与4''-碘苯并-15-冠-5固态配合物的合成与性质[J]. 无机化学学报, 1987, 3(4): 132-137 |
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| 作者姓名： | 卢爱茹 张联祥 张卫锴 缪荣生 王流芳 晏国洪 |
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| 作者单位： | 西北师范学院化学系，西北师范学院化学系，西北师范学院化学系，西北师范学院化学系，兰州大学化学系，兰州大学化学系 兰州，兰州，兰州 八六届毕业生，兰州 八六届毕业生，兰州，兰州 |
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| 摘 要： | 对碱金属、希土与苯并-15-冠-5冠醚配合物的研究指出,4′-取代单苯并冠醚的阳离子配合物的稳定性及其他性质,受取代基电子效应的影响,给电性取代基可增加芳醚氧原子上的电子密度,改变冠氧的极性,从而影响其配位能力,扩大希土配合物之间性质上的差别,达到分离的目的。对于铁系元素,文献报导甚少。我们继Ⅰ之后,又合成了三氯化铁水合物与4′-碘苯并-15-冠-5固态配合物,并研究了其性质。
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| 关 键 词： | 铁系元素 配合物 冠醚配合物 |
| 收稿时间： | 1986-10-03 |
STUDIES ON IRON SERIES COORDINATION COMPOUNDS WITH CROWN ETHER II. SYNTHESIS AND PROPERTIES OF IRON SERTIES CHLORIDES WITH 4''-IODOBENZO-15-CROWN-5(L)COORDINATION COMPOUND IN SOLID STATE |
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| Lu Airu,Zhang Lianxiang,Zhang Weikai,Miu Rongsheng,Wang Liufang and Yan Guohong. STUDIES ON IRON SERIES COORDINATION COMPOUNDS WITH CROWN ETHER II. SYNTHESIS AND PROPERTIES OF IRON SERTIES CHLORIDES WITH 4''-IODOBENZO-15-CROWN-5(L)COORDINATION COMPOUND IN SOLID STATE[J]. Chinese Journal of Inorganic Chemistry, 1987, 3(4): 132-137 |
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| Authors: | Lu Airu Zhang Lianxiang Zhang Weikai Miu Rongsheng Wang Liufang Yan Guohong |
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| Affiliation: | Department of Chemistry, Northwestern Teacher's College, Lanzhou,Department of Chemistry, Northwestern Teacher's College, Lanzhou,Department of Chemistry, Northwestern Teacher's College, Lanzhou,Department of Chemistry, Northwestern Teacher's College, Lanzhou,Department of Chemistry, Lanzhou University, Lanzhong and Department of Chemistry, Lanzhou University, Lanzhong |
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| Abstract: | The synthesis and properties of coordination compounds of iron series chlorides(FeCl3·CoCl2 and NiCl2)with 4'-iodobenzo-15-crown-5 were reported in this paper.Synthesized FeCl3·L·3H2O is a new kind of 1:1 crown ether coordination compound. Which contains three moles crystal water and characterized by element analysis, IR spectrum, UV spectrum, DTA TG and X-ray.Under the same conditions, the coordination compounds of CoCl2 and NiC12 with 4'-iodobenzo-15-crown-5 were not formed. |
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| Keywords: | iron series element coordination compound crown ether coordination compound |
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