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Biomimetic transformation of gentiopicroside to erythrocentaurin
Authors:Cui Ling Wanga Jian Li Liu Zhu Lan Liua Xin Sheng Lib Xiao Yong Caob a School of Life Science  Northwest University  Xi'an  China b
Institution:a School of Life Science, Northwest University, Xi'an 710069, China;b Department of Biology, Shaanxi University of Technology, Hanzhong 723001, China
Abstract:Biomimetic transformation of gentiopicroside was carried out by β-glueosidase at pH 7.0 for 3 days at 37 ℃.Two products,erythrocentaurin and 5,6-dihydro-5-formy|-6-methyl-1H,3H-pyrano3,4-c]pyran-1-one were isolated and identified by 1H NMR,13C NMR,UV,IR,MS and elemental analyse.The possible mechanisms were discussed.
Keywords:Genfiopicroside  Biomimetic transformation  Erythrocentaurin  5  6-Dihydro-5-formyl-6-methyl-lH  3H-pyrano[3  4-c]pyran-1-one
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