Synthesis of functionalized dioxa-aza[7]helicenes using palladium catalyzed arylations |
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Authors: | Kelgtermans Hans Dobrzańska Liliana Van Meervelt Luc Dehaen Wim |
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Affiliation: | Molecular Design and Synthesis, Department of Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium. |
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Abstract: | Despite the recent reports on transition-metal catalyzed cycloisomerization strategies toward helicenes, the amount of palladium catalyzed routes remains rather scarce. Within this letter the successful preparation and characterization of novel dioxa-aza[7]helicenes using palladium mediated coupling reactions is presented. |
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