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A formal synthesis of (+)-didemniserinolipid B employing a Pd-mediated 6-endo selective alkynediol cycloisomerization |
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| Authors: | C.V. Ramana Boddeti Induvadana |
| Affiliation: | National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411 008, India |
| Abstract: | Herein, we describe a concise assembly of central 6,8-dioxabicyclo[3,2,1]octane core of didemniserinolipid by employing a Pd-mediated alkynediol cycloisomerization and a formal total synthesis of didemniserinolipid B. |
| Keywords: | Didemniserinolipid Bridged bicyclic ketal Alkynol cycloisomerization Zipper reaction Yamaguchi oxirane-alkyne coupling |
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