Synthesis, characterization and nonlinear optical properties of nonaggregating hexadeca-substituted phthalocyanines |
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| Authors: | Saad Makhseed Moyyad Al-Sawah Hacene Manaa |
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| Affiliation: | a Chemistry Department, Kuwait University, PO Box 5969, Safat 13060, Kuwait
b Physics Department, Kuwait University, PO Box 5969, Safat 13060, Kuwait |
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| Abstract: | The microwave-assisted synthesis, characterization and photophysical properties of hexadeca-substituted phthalocyanine (Pc) complexes with bulky phenoxy substituents are reported. NMR and UV-Vis analyses confirm the ability of bulky groups to induce steric isolation of Pc cores even in the solid state. The Z-scan measurement indicates that the Zn-containing derivative has promising nonlinear optical properties (NLOs). |
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