Fourier transform infrared study of segmental orientation in polymer blends |
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Authors: | Paul Chabot Michel Pézolet Robert E Prud'homme |
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Institution: | (1) Centre de Recherche en Sciences et Ingénierie des Macromolécules, Département de Chimie, Université Laval, G1K 7P4 Sainte-Foy, Québec, Canada |
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Abstract: | The effect of the macromolecular plasticizer poly( -methyl- -n-propyl- -propiolactone), PMPPL, on the orientation of poly(vinyl chloride), PVC, has been studied by FTIR spectroscopy. The addition of PMPPL to PVC does not change significantly the degree of orientation of PVC segments. In blends, PMPPL chains are more oriented when the matrix is richer in PVC but the PMPPL orientation function always remains smaller than that of PVC segments. |
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Keywords: | orientation FTIR polymer blends PVC PMPPL |
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