Transformation of an irregularly bridged epidithiodiketopiperazine to trichodermamide A |
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| Authors: | Seephonkai Prapairat Kongsaeree Palangpon Prabpai Samran Isaka Masahiko Thebtaranonth Yodhathai |
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| Institution: | Department of Chemistry, Faculty of Science, Mahidol University, Bangkok, Thailand. |
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| Abstract: | reaction: see text] An unusually bridged epidithiodiketopiperazine, pretrichodermamide A (3), was isolated from the fungus Trichoderma sp. BCC 5926. During the extensive effort to crystallize 3 for X-ray crystallographic analysis, conversion of this compound to trichodermamide A with coproduction of S(8) occurred. |
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