Desymmetrization of meso-dialdehydes with optically active cyclopentadienyldialkoxyallyltitanium complexes |
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| Authors: | BouzBouz Popkin Cossy |
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| Affiliation: | Laboratoire de Chimie Organique associe au CNRS, ESPCI, 10 rue Vauquelin, 75231 Paris Cedex 05, France. |
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| Abstract: | Optically active cyclopentadienyldialkoxyallyltitanium complexes have been employed for the desymmetrization of meso-dialdehydes. Allylation of these dialdehydes and subsequent oxidation afford chiral lactones with good diastereoselectivity and excellent enantioselectivity. |
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