Stereoselective photocycloaddition of alkenes to naphthalene rings assisted by hydrogen bonding |
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Authors: | Yokoyama Mizuno |
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Affiliation: | Department of Applied Chemistry, College of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Sakai, Osaka 599-8531, Japan. |
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Abstract: | Introduction of a hydrogen-bonding substituent to 1-cyanonaphthalene and alkene resulted in the selective formations of endo-photocycloadducs. Furthermore, the yield and selectivity were improved as the reaction temperature was lowered. |
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