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Strong correlations in electron doped phthalocyanine conductors near half filling
Authors:Tosatti Erio  Fabrizio Michele  Tóbik Jaroslav  Santoro Giuseppe E
Affiliation:International School for Advanced Studies (SISSA) and INFM Democritos National Simulation Center, Via Beirut 2-4, I-34014 Trieste, Italy.
Abstract:We propose that electron doped nontransition metal phthalocyanines such as ZnPc and MgPc, similar to those very recently reported, should constitute novel strongly correlated metals. Because of orbital degeneracy, Jahn-Teller coupling, and Hund's rule exchange, and with a large on-site Coulomb repulsion, these molecular conductors should display, particularly near half filling at two electrons/molecule, very unconventional properties, including Mott insulators, strongly correlated superconductivity, and other intriguing phases.
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