The total synthesis of 13(R)- and 13(S)-dihydro-4-demethoxy-daunorubicin. Revision of stereochemistry of the microbial and mammalian reduction product of 4-demethoxydaunorubicin |
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| Authors: | Michael J Broadhurst Cedric H Hassall Gareth J Thomas |
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| Institution: | Roche Products Ltd, PO Box 8, Welwyn Garden City, Herts Great Britain |
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| Abstract: | The properties of 13(S)-dihydro-4-demethoxydaunorubicin, rather than the 13(R)-isomer, correspond to those of the microbial and mammalian reduction product of 4-demethoxydauno-rubicin. |
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