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CRYSTALLIZATION CHARACTERISTICS OF β-PHASE CRYSTALS IN COPOLYMERS OF POLYPROPYLENE WITH LOW ETHYLENE CONTENT
作者姓名:Wen-tao Hao  Yi-yong He  Xiao-lie Luo  De-zhu Ma Department of Polymer Science and Engineering University of Science and Technology of China Hefei 230026 China
摘    要:Polypropylene copolymers (CPP) containing β-nucleating agent were investigated by differential scanningcalorimetry (DSC), wide-angle X-ray diffraction (WAXD) and polarizing light microscopy (PLM). The results show thathigh content of β-phase crystals can also be formed for CPPs. Like PP homopolymers, the CPPs also have a most favorabletemperature near 132℃ for β-phase crystal growth. The crystallization rate of CPPs containing β-nucleating agent (β-CPP) ismuch greater than that of PP homopolymer containing β-nucleating agent (β-PP homopolymer). The observation ofspherulite morphology of β-CPP and β-PP homopolymer shows that the spherulites of β-CPP are more imperfect than thoseof β-PP homopolymer.

关 键 词:Copolymer polypropylene  β-Nucleating agent  Differential scanning calorimetry  Wide angle X-ray diffraction  Spherulite
收稿时间:2001-02-02
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